CO2 as a reaction ingredient for the construction of metal cages: a carbonate-panelled [Gd6Cu3] tridiminished icosahedron.

CO2 as a reaction ingredient for the construction of metal cages: a carbonate-panelled [Gd6Cu3] tridiminished icosahedron.

A CO32–panelled [(Gd6Cu3II)-Cu-III] cage conforming to a tridiminished icosahedron is synthesised by bubbling CO2 through a solution of Gd-III and Cu-II ions.