Slow magnetic relaxations in a ladder-type Dy(III) complex and its dinuclear analogue.

Slow magnetic relaxations in a ladder-type Dy(III) complex and its dinuclear analogue.

The complex {[Dy-2(PDOA)(3)(H2O)(6)]center dot 2H(2)O}(n) (1) (H(2)PDOA = 1,2-phenylenedioxydiacetic acid) was prepared from aqueous solution. Its crystal structure, built up of {-Dy-O-C-O-}(n) chains interlinked by PDOA ligands yielding a ladder-like arrangement, was determined at 173 K. 1 exhibits slow magnetic relaxation under a small magnetic field B-DC = 0.2 T with two (LF and HF) relaxation channels. The LF relaxation time at B-DC = 0.2 T and T = 1.85 K is as slow as tau(LF) = 46 ms whereas the HF channel is tau(HF) = 1.4 ms. The mole fraction of the LF species is x(LF) = 0.76 at 1.85 K and it escapes progressively on heating. In the dinuclear analogue [Dy-2(PDOA)(3)(H2O)(6)]center dot 3.5H(2)O (2) one PDOA ligand forms a bis(chelate) bridge between the two Dy(III) atoms yielding a local structure analogous to that in 1; however its AC susceptibility data show slightly different quantitative characteristics of the single-molecule magnetic behaviour.